Title
Barium Nuclear Magnetic Resonance Spectroscopic Study of YBa2Cu3O7
Document Type
Article
Publication Date
7-1992
Abstract
We have measured the 135Ba nuclear magnetic resonance (NMR) line shape and the 137Ba nuclear quadrupole resonance (NQR) of a powder sample of YBa2Cu3O7, at 300 K, as well as the temperature and field dependences of the 135,137Ba NMR line shapes and spin-lattice relaxation rates of magnetically aligned (c?H0) samples, in the normal and superconducting states. From the NQR and the field and isotopic dependences of the NMR line shapes of magnetically aligned samples at 300 K, we conclude that the magnetic shift is small (0.0±0.12%), and that the principal components of the electric-field gradient tensor are ±(8.3,-0.2,-8.1)×1021 V m−2, with the largest component coincident with the crystallographic c axis. In the superconducting state, the resonances broaden and are shifted to lower frequency. The spin-lattice relaxation behavior is not Korringa-like above Tc, and may be influenced by spin fluctuations in the CuO2 plane.
Publication Title
Physical Review B
Volume
46
First Page
595
Last Page
598
DOI of Published Version
10.1103/PhysRevB.46.595
Recommended Citation
Shore, Jay S.; Yang, Shengtian; Haase, Jürgen; Schwartz, Dwight; and Oldfield, Eric, "Barium Nuclear Magnetic Resonance Spectroscopic Study of YBa2Cu3O7" (1992). Chemistry and Biochemistry Faculty Publications. 90.
https://openprairie.sdstate.edu/chem_pubs/90