"Determination of Quadrupolar and Chemical Shielding Tensor Elements Us" by Jay S. Shore, S. H. Wang et al.
 

Title

Determination of Quadrupolar and Chemical Shielding Tensor Elements Using Solid State Two-Dimensional NMR Spectroscopy

Document Type

Article

Publication Date

6-1996

Abstract

The quadrupolar and chemical shift tensors, as well as the relative orientation of the two principle axis systems, are accurately determined using a two‐dimensional nuclear magnetic resonance technique. Good agreement between experimental and simulated two‐dimensional spectra is obtained for a series of rubidium and sodium compounds at multiple magnetic field strengths. Extension of this technique to correlate the quadrupolar and dipolar interactions, as well as the incorporation of a purely isotropic dimension resulting in a three‐dimensional experiment is also discussed.

Publication Title

Journal of Chemical Physics

Volume

105

First Page

9412

Last Page

9420

DOI of Published Version

10.1063/1.472776

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